期刊
INORGANIC CHEMISTRY
卷 46, 期 25, 页码 10476-10478出版社
AMER CHEMICAL SOC
DOI: 10.1021/ic702007r
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The iron phosphine complex cis-[Fe(DMeOPrPE)(2)(eta(2)-N2H4)][BPh4](2) {DMeOPrPE = 1,2-bis[bis(methoxypropyl)phosphino]ethane} was synthesized and structurally characterized. The structure exhibits the first eta(2) coordination of hydrazine to iron, which may be relevant to intermediates trapped during nitrogenase turnover. The reaction of I with acid results in the formation of ammonia via a disproportionation reaction.
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