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Giant enhancement in low energy photoemission of Ar confined in C60

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PHYSICAL REVIEW LETTERS
卷 99, 期 24, 页码 -

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AMER PHYSICAL SOC
DOI: 10.1103/PhysRevLett.99.243003

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Considering an Ar atom endohedrally sequestered in C(60), a phenomenal increase in the photoionization cross section of the confined atom through the dominant outer 3p channel is predicted. The effect occurs owing to a powerful dynamical coherent interchannel coupling between the atomic and the cage ionization channels which redirects the bulk of oscillator strength from the giant surface plasmon to the atomic ionization.

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