期刊
TETRAHEDRON
卷 63, 期 51, 页码 12740-12746出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tet.2007.09.078
关键词
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An optically active octahydroindole, the core unit of aeruginosins (Choi) was synthesized. The Diels-Alder reaction of Danishefsky's diene with methyl (Z)-2-acetamido-2,4-pentadienoates provided the adducts regioselectively in good yield. The adducts were converted to the L-Choi precursor by asymmetric hydrogenation, followed by acid cyclization. (c) 2007 Elsevier Ltd. All rights reserved.
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