期刊
ORGANIC LETTERS
卷 9, 期 26, 页码 5477-5480出版社
AMER CHEMICAL SOC
DOI: 10.1021/ol702401w
关键词
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资金
- NIGMS NIH HHS [R01 GM078383, R01 GM078383-02, R01-GM078383] Funding Source: Medline
The copper(II) carboxylate-promoted intramolecular carboamination reactions of variously substituted gamma-alkenyl amides have been investigated. These oxidative cyclization reactions efficiently provide polycyclic lactams, useful intermediates in nitrogen heterocycle synthesis, in good to excellent yields. The efficiency of the carboamination process is dependent upon the structure of the amide backbone as well as the nitrogen substituent.
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