期刊
JOURNAL OF ORGANIC CHEMISTRY
卷 72, 期 26, 页码 10294-10297出版社
AMER CHEMICAL SOC
DOI: 10.1021/jo702076j
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[GRAPHICS] A concise and efficient approach to the stereodivergent synthesis of (+)-lasubines I and II is described. The key common intermediate is a chiral N-sulfonyl 2,3-dihydropyridone obtained by a novel Cu-catalyzed asymmetric formal aza-Diels-Alder reaction between N-tosyl aldimines and Danishefsky's diene.
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