期刊
JOURNAL OF ORGANIC CHEMISTRY
卷 72, 期 26, 页码 10243-10246出版社
AMER CHEMICAL SOC
DOI: 10.1021/jo702019p
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Quaterrylenedicarboximides were prepared from 9-bromoperylene-3,4-dicarboximides by palladium-catalyzed coupling with 3-perylene boronic ester, followed by oxidative cyclo-dehydrogenation of the resulting perylene-perylenedicar-boximide dyads with iron(III) chloride. The quaterrylenedi-carboximides, described here, are highly photochemically and thermally stable dyes, which may be useful as green NIR dyes (lambda(max) = 735 nm) and as building blocks for the synthesis of higher rylene dyes.
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