期刊
INORGANIC CHEMISTRY
卷 46, 期 26, 页码 11366-11370出版社
AMER CHEMICAL SOC
DOI: 10.1021/ic701688t
关键词
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An improved method for deconvoluting energy-resolved collision-induced dissociation cross sections yields ligand binding energies for organometallic complexes with substantially less prior information than before. Application to isomeric 2:1 complexes of azabox ligands with Cu(I) gives consistent results for the binding energies of the ligands to homo- and heterochiral complexes with pseudo-enantiomeric ligands for cases where previous deconvolution methods had failed to give satisfactory results.
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