期刊
CHINESE JOURNAL OF CATALYSIS
卷 29, 期 2, 页码 105-107出版社
SCIENCE CHINA PRESS
DOI: 10.1016/S1872-2067(08)60019-4
关键词
formic acid; platinum; titanium dioxide; photocatalysis; infrared spectroscopy
The anaerobic photocatalytic decomposition of formic acid to hydrogen on Pt/TiO2 was studied by in situ FT-IR spectroscopy. The molecularly adsorbed formic acid species is transformed to a formate species, and the formate species is transformed to carbonates during this reaction. The addition of water vapor in the reaction system strongly accelerates this photocatalytic reaction and promotes the H-2 production efficiency. The possible mechanism of the reaction is proposed.
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