期刊
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY
卷 40, 期 33, 页码 10536-10541出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.ijhydene.2015.06.158
关键词
Lithium borohydride; Reactive hydride system; Hydrogen storage property; Reaction mechanism
资金
- National Natural Science Foundation of China [51371008]
In this paper, the 4LiBH(4)-LiAlH4-MgF2 ternary reactive system was constructed to investigate its de-/rehydrogenation properties and reaction mechanisms. It was found that the 4LiBH(4)-LiAlH4-MgF2 system starts to release hydrogen at about 100 degrees C and totally desorbs about 8.9 wt.% of hydrogen up to 480 degrees C. These dehydrogenation properties are much better than those of the 2LiBH(4)-LiAlH4, 2LiBH(4)-MgF2 and 4LiBH(4)-LiAlH4-MgF2 systems. Thermal dehydrogenation of the 4LiBH(4)-LiAlH4-MgF2 system proceeds mainly in three steps with MgAlB4, LiH and LiF as the desorbed products. After rehydrogenation at 400 degrees C under 6 MPa hydrogen pressure, about 4.9 wt.% of hydrogen can be desorbed during the second dehydrogenation process. Copyright (C) 2015, Hydrogen Energy Publications, LLC. Published by Elsevier Ltd. All rights reserved.
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