期刊
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY
卷 40, 期 33, 页码 10542-10546出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.ijhydene.2015.06.109
关键词
Zr-fumarate MOF; Modulated synthesis; Pore size distribution; Hydrogen storage
资金
- South African Department of Science and Technology (DST) [HTC004X]
- National Research Foundation (NRF) through the South Africa/China research collaboration grant [HTC059X]
- Council for Scientific and Industrial Research (CSIR) [HTC066P]
In this work, we synthesized Zr-fumarate MOFs by applying water as solvent and formic acid as modulator. Highly crystalline Zr-fumarate MOF obtained from 120 degrees C, 24 h synthesis conditions showed high thermal and hydro stabilities. Compared to the early reported MOF materials, the lower cost, more environmentally friendly synthesis process and comparable hydrogen uptake capacity make Zr-fumarate MOFs a good candidate for hydrogen storage applications. Copyright (C) 2015, Hydrogen Energy Publications, LLC. Published by Elsevier Ltd. All rights reserved.
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