期刊
CELLULOSE
卷 15, 期 1, 页码 81-89出版社
SPRINGER
DOI: 10.1007/s10570-007-9142-z
关键词
cellulose; NaOH/urea aqueous solution; multi-filament fibers; green process; finishing oil
Cellulose multi-filament fibers have been spun successfully on a pilot plant scale, from a cellulose dope in 7 wt% NaOH/12 wt% urea aqueous solution pre-cooled to -12 degrees C. Coagulation was accomplished in a bath with 10 wt% H2SO4/12 wt% Na2SO4 and then 5 wt% H2SO4 aqueous solution. By using different finishing oil, including H2O, 4% glycerol aqueous solution, 2% polyvinyl alcohol (PVA) aqueous solution, 2% polyethylene glycol octyl phenylether (OP) aqueous solution, mobol and 2%glycerol/1%PVA/1%OP aqueous solution (PGO), we prepared six kinds of the cellulose multi-filaments, with tensile strength of 1.7-2.1 cN/dtex. Their structure and properties were investigated with scanning electron microscope (SEM), C-13 NMR solid state, wide-angle X-ray diffraction (WAXD) and tensile testing. The cellulose fibers treated with PGO possessed higher mechanical properties and better surface structure than others. Interestingly, although the orientation of the cellulose multi-filaments is relatively low, the tensile strength of the single-fiber was similar to that of Lyocell. It was worth noting that the dyeability of the multi-filament fibers was superior to viscose rayon.
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