期刊
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY
卷 40, 期 8, 页码 3528-3537出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.ijhydene.2014.09.017
关键词
Composite palladium membrane; Hydrogen separation; Recycling; Reuse; Electroless plating
资金
- Natural Science Foundation of Jiangsu Province, China [BK20130940, BK20130916]
The increasing applications of hydrogen energy greatly promote the development of composite palladium membranes, which are ideal for hydrogen purification because of their high permeability, excellent permselectivity and easy modulation. However, these membranes are still associated with problems such as high cost and limited operating life. This work investigates membrane recycling and reuse as a solution to these problems. Pd/Al2O3 membranes were prepared by electroless plating. The recycling of palladium was achieved by treating it with HNO3 and HCl-H2O2 agents. Adequate results were achieved using an agent composed of 2 mol/L HCl and 1 mol/L H2O2. The recycled palladium can be utilized in a new plating bath, while the Al2O3 substrate remaining after palladium recycling can be reused as the substrate material for the preparation of new membranes. The surface morphology, thickness and permeation performances of the recycled membranes, as characterized by scanning electron microscopy, metallographic microscopy and permeation tests, are similar to those of the original palladium membranes. It can be concluded that the recycling and reuse of the Pd/Al2O3 membranes are successful and may provide a solution to the current key problems associated with the application of composite palladium membranes. Copyright (C) 2014, Hydrogen Energy Publications, LLC. Published by Elsevier Ltd. All rights reserved.
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