期刊
JOURNAL OF APPLIED POLYMER SCIENCE
卷 107, 期 3, 页码 1954-1959出版社
WILEY-BLACKWELL
DOI: 10.1002/app.26643
关键词
cellulose; N-methylmorpholine-N-oxide (NMMO); electrospinning; crystal structure; poly(butylene succinate) (PBS); biocomposite
资金
- Ministry of Knowledge Economy (MKE), Republic of Korea [KIER-A82417] Funding Source: Korea Institute of Science & Technology Information (KISTI), National Science & Technology Information Service (NTIS)
- National Research Foundation of Korea [핵06B1310] Funding Source: Korea Institute of Science & Technology Information (KISTI), National Science & Technology Information Service (NTIS)
In this study, electrospinning conditions for ultrafine cellulose fibers was systematically studied and poly(butylene succinate) biocomposites reinforced by the ultrafine cellulose fibers (cellulose/PBS biocomposite) were fabricated. The ultrafine cellulose fibers were electrospun from cellulose (DP = 700) solutions in N-methylmorpholine-N-oxide hydrate (85/15 w/w) at 100 degrees C. The optimal electrospinning concentration of the cellulose solutions was determined to be 7 wt % and the average diameter of the resulting cellulose fibers was 560 rim. The cellulose I structure of the native cellulose was converted to the cellulose II structure after electrospinning. The ultrafine cellulose fibers showed a reinforcing effect in the cellulose/PBS biocomposite, suggesting that they have potential applications as reinforcement fibers for biocomposites. (c) 2007 Wiley Periodicals, Inc.
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