期刊
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY
卷 40, 期 32, 页码 10262-10273出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.ijhydene.2015.06.052
关键词
Nickel; Electroless deposition; Tin oxide; Electrochemical impedance spectroscopy; Methanol oxidation; KOH
Ni-P-SnO2/C composite was prepared by electroless reduction of nickel ions on SnO2/C powder. The weight percentage of SnO2 in the prepared composite was varied as 2.5-20. Scanning electron microscopy (SEM) and energy dispersive X-ray (EDX) analysis were employed to investigate the morphology, particle size and chemical composition of Ni-P SnO2/C composite. Nickel islands with an average diameter of 0.33 gm were formed in the composite containing 10 wt.% SnO2 [Ni P SnO2/C-10]. The electrochemical performance of Ni P SnO2/C composite in KOH solution was studied using cyclic voltammetry and electrochemical impedance spectroscopy (EIS). Its electron transfer coefficient and electron transfer rate constant values were determined as a function of SnO2 weight percentage. The impedance value was found to gradually decrease with increasing SnO2 content getting its lowest value in Ni P SnO2/C-10 composite. The effect of altering the sweeping potential and KOH concentration on NiOOH film thickness in Ni P SnO2/C composite was investigated. An enhanced electrocatalytic activity of the prepared composite towards methanol oxidation in KOH solution was shown. In presence of methanol, the diameter of semi-circle was greatly reduced to record a much lowered Rct value of 0.25 0 cm(2). Copyright (C) 2015, Hydrogen Energy Publications, LLC. Published by Elsevier Ltd. All rights reserved.
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