期刊
ACS APPLIED MATERIALS & INTERFACES
卷 7, 期 6, 页码 3480-3491出版社
AMER CHEMICAL SOC
DOI: 10.1021/am508540x
关键词
one-pot; three-dimensional graphene nanohybrids; dual-enzyme activity; colorimetry; glucose
资金
- National Nature Science Foundation of China [21475053]
The self-assembled three-dimensional graphene nanohybrids with in situ-formed Fe3O4 and Pd nanoparticles on it (3DRGO_Fe3O4-Pd) are first synthesized by the one-pot solvothermal method, which have intrinsic peroxidase-like and oxidase-like activity. The catalytic mechanism is analyzed by the electron spin resonance (ESR), fluorescence, and electrochemical methods. The mimic enzyme catalytic activity of 3DRGO_Fe3O4-Pd is much higher than those of monometallic loaded nanohybrids and their physical mixture, probably caused by synergistic effect between Pd and Fe3O4 nanoparticles. The 3DRGO_Fe3O4-Pd nanohybrids was reproducible, stable, and reusable. After 10 cycles, the catalytic activity was still higher than 90%, and the morphology and structure were basically unchanged. Based on its high peroxidase-like activity, especially the enhanced affinity toward H2O2, a new colorimetric detection method for reduced glutathione (GSH) and glucose has been designed using H2O2 as an intermediary, which provides a simple, sensitive, and selective way to detect urine glucose of diabetes with a wide linear range and low detection limit.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据