期刊
ARKIVOC
卷 -, 期 -, 页码 187-198出版社
ARKAT USA INC
DOI: 10.3998/ark.5550190.0010.816
关键词
1,1-Bis(phenylsulfonyl)ethylene; beta-syn-addition; beta-syn-elimination; sulfenic acids
资金
- Universita degli Studi di Messina
The use of 2,2-bis(phenylsulfonyl)ethyl sulfides as efficient precursors of sulfenic acids is reported. These starting compounds, carrying both sulfone and sulfide residues, are obtained in one step from commercially available thiols and 1,1-bis(phenylsulfonyl)ethylene. Mild decomposition of the derived 2,2-bis(phenylsulfonyl)ethyl sulfoxides to sulfenic acids, in the presence of suitable acceptors, opens the way to the generation of a wide library of new sulfoxides not easily accessible through different synthetic pathways.
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