期刊
JOURNAL OF THE CERAMIC SOCIETY OF JAPAN
卷 117, 期 1371, 页码 1175-1179出版社
CERAMIC SOC JAPAN-NIPPON SERAMIKKUSU KYOKAI
DOI: 10.2109/jcersj2.117.1175
关键词
Photocatalyst; Perovskite; Visible light response; Codoping; Hydrogen production
Layered perovskite Ca3Ti2O7 codoped with Rh and Ln (Ca(3-x)Ln(x)Ti(1.9)Rh(0.1)O(7); Ln = La, Pr, Nd, Eu, Gd, Yb, and Y; 0 <= x <= 0.15) was synthesized by a conventional solid-state reaction to investigate the effects of Rh and Lit codoping on the photocatalytic activity. Rh and Ln-codoped Ca3Ti2O7 exhibited a higher photocatalytic activity than Rh-doped Ca3Ti2O7 for H-2 production from an aqueous methanol solution under visible light irradiation (lambda > 420 nm). In addition, the induction period for H-2 production was shortened by codoping with Rh and Ln. The codoped elements helped control the oxidation state of Rh ions and suppressed the formation of oxygen defects, improving the activity of the Rh-doped Ca3Ti2O7 photocatalyst. (C) 2009 The Ceramic Society of Japan. All rights reserved.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据