Surface shear rheology of monolayers at the surface of water

The knowledge of surface shear rheology is important to understand and model flow in systems where interfaces are present: multiphase flow, wetting, foaming and others. The topic has been investigated for more than 100 years, but the knowledge accumulated is still partial. The experimental devices used for the measurement of the viscoelastic parameters are delicate to operate and the response of the monolayers is complex, usually non-linear and time dependent. Furthermore, it is difficult to decouple from the response of the bulk liquid. Important discrepancies between microscopic and macroscopic methods were reported and remain to be clarified. The knowledge of shear properties does not suffice in general to achieve proper descriptions of the flow behavior and measurements of compression properties are needed as well. This paper presents examples taken from the literature and discusses the current level of understanding. (C) 2013 Elsevier B.V. All rights reserved.