期刊
ADVANCED SYNTHESIS & CATALYSIS
卷 360, 期 18, 页码 3590-3594出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adsc.201800804
关键词
phosphorylation; C-H functionalization; DDQ; cross-dehydrogenative coupling; allylphosphonates
资金
- Science and Technology Planning Project of Guangdong Province [2015 A020211026, 2017 A010103044]
- 100 Young Talents Programme of Guangdong University of Technology [220413506]
- Open Fund of the Key Laboratory of Functional Molecular Engineering of Guangdong Province (South China University of Technology) [2016kf07]
An efficient allylic C-H phosphorylation has been achieved through the DDQ-promoted cross-dehydrogenative coupling of 1,3-diarylpropenes with P(O)H compounds at room temperature. This method provides a convenient route to allylphosphonates in up to 97% yield with good functional group compatibility.
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