期刊
ADVANCED SYNTHESIS & CATALYSIS
卷 360, 期 18, 页码 3460-3465出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adsc.201800414
关键词
1,2-Aryl Migration; Radical reactions; Oxidation; Transition metals; Pyrrolo[1.2-alpha]indole derivatives
资金
- National Science Foundation [NSF 21472073, 21532001, 21772075]
A novel copper-catalyzed cascade radical sulfonylation of N-propargyl-substituted indoles with concomitant 1,2-aryl migration was described. The protocol, which has good functional-group tolerance, provides practical, versatile and atom-economical method of accessing a new class of fascinating 2-sulfonated pyrrolo[1.2-alpha] indole derivatives in moderate to good yields through the formation of the new C-S, C-C and C=O bonds in a one-step.
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