期刊
ADVANCED SYNTHESIS & CATALYSIS
卷 360, 期 5, 页码 901-904出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adsc.201701201
关键词
Pyrazole; Iodine; Peroxide; Cyclization; Metal-free
资金
- Natural Science Foundation of China [21602197]
- Natural Science Foundation of Zhejiang Province [LY15B020004, LY18B020018]
The tandem reaction of 3-morpholinoa-crylonitrile with sulfonyl hydrazides mediated by I-2/benzoyl peroxide (BPO) is reported, which offers an efficient approach for the synthesis of sulfonated 5-aminopyrazoles. It can bear a large scope of the substrates, and be used for the synthesis of aromatic, heteroaromatic and aliphatic sulfonated 5-aminopyrazoles.
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