期刊
ADVANCED SYNTHESIS & CATALYSIS
卷 360, 期 20, 页码 3900-3905出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adsc.201800823
关键词
bioinspired reactions; C-H activation; deamination; synthetic methods
资金
- National Natural Science Foundation of China [21502089]
- Jiangsu Province Funds Surface Project [BK 20161541]
- Starting Funding of Research from Nanjing Tech University [39837107]
- SICAM Fellowship by Jiangsu National Synergetic Innovation Center for Advanced Materials
An efficient bioinspired deamination method of both natural and unnatural amino acid derivatives has been developed. This method provides easy access to a wide variety of useful alpha, beta-unsaturated carbonyl compounds. The reaction is realized with two transition metal catalysts (palladium and Nickel) in-easy handling procedure. A possible reaction pathway is also proposed and the control experiments support the involvement of the palladium-catalyzed inert sp(3) C-H activation as one of the key steps.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据