期刊
ADVANCED SYNTHESIS & CATALYSIS
卷 360, 期 23, 页码 4585-4593出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adsc.201800954
关键词
Green chemistry; Carbonylation; Urea synthesis; Micellar catalysis; Water
资金
- National Natural Science Foundation of China [21302014, 21676030]
- China Postdoctoral Science Foundation [2018 M632289]
- Jiangsu Key Laboratory of Advanced Catalytic Materials and Technology [BM2012110]
- Priority Academic Program Development (PAPD) of Jiangsu Higher Education Institutions
- Advanced Catalysis and Green Manufacturing Collaborative Innovation Center of Changzhou University
A Pd/C-catalyzed domino synthesis of symmetrical and unsymmetrical ureas from aryl iodides, sodium azide, amines and CHCl3 in water has been developed. This reaction proceeds with sequential carbonylation, Curtius rearrangement and nucleophilic addition. CHCl3 serves as a convenient and safe alternation of CO gas in the presence of KOH. A series of urea derivatives were obtained in moderate to good yields with good functional group tolerance. Furthermore, the Pd/C catalyst could be readily recovered with slight decrease in the catalytic activity after six consecutive runs.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据