期刊
ADVANCED SYNTHESIS & CATALYSIS
卷 361, 期 3, 页码 405-425出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adsc.201800789
关键词
dearomative cyclization; fused indolines; ring contraction; synthetic methods; transition metal catalysis
资金
- National Program on Key Research Project [2016YFA0602900]
- National Natural Science Foundation of China [21572068]
- Science and Technology Program of Guangzhou, China [201707010057]
- Guangdong Natural Science Foundation [2017A030312005]
- Science and Technology Planning Project of Guangdong Province, China [2017A020216021]
Fused polycyclic indoline skeletons are found in many natural products and bioactive molecules. Several approaches, including dearomative cyclization of functionalized indoles, have been developed for the rapid synthesis of these skeletons. As a result of extensive research over the past few decades, numerous elegant and efficient protocols for the transition metal-catalyzed dearomative cyclization of indoles to afford indolines have been reported, and recent developments in this area are discussed in detail in this review.
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