期刊
ADVANCED SYNTHESIS & CATALYSIS
卷 356, 期 8, 页码 1873-1877出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adsc.201300841
关键词
aqueous conditions; homogeneous catalysis; N-heterocyclic carbenes; palladium; Suzuki-Miyaura coupling
资金
- Alexander von Humboldt-Foundation
The application of a highly active Pd-NHC catalyst for the Suzuki-Miyaura cross-coupling of a broad variety of electronically activated and deactivated aryl chlorides with different arylboronic acids in excellent yields is described. This catalyst can be handled under aerobic conditions, is active with low catalyst loadings at room temperature and in an aqueous reaction medium and allows the application of cheap potassium carbonate as the base.
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