期刊
ADVANCED SYNTHESIS & CATALYSIS
卷 356, 期 6, 页码 1229-1234出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adsc.201300855
关键词
carbenes; catalysis; gold; oxidation; thiazoles
资金
- NSF [CHE1301343, CHE-0969157]
- Government of Jiangsu, China
- NSFC [21003073]
- Division Of Chemistry
- Direct For Mathematical & Physical Scien [1301343] Funding Source: National Science Foundation
By using Mor-DalPhos as the P,N-bidentate ligand and mesylate as the counter ion, the resulting gold(I) complex catalyzes efficient oxidative transformations of various terminal alkynes into synthetically versatile methanesulfonyloxymethyl ketones. The mild reaction conditions and high efficiency permit the one-pot synthesis of a range of valuable 2,4-disubstituted thiazoles by subjecting the resulting reaction mixture to a further condensation with thioamides under mild conditions.
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