期刊
ADVANCED SYNTHESIS & CATALYSIS
卷 356, 期 1, 页码 160-164出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adsc.201300712
关键词
cycloaddition; isoxazoles; isoxazolines; PEG; polyethylene glycol; water
A 1:1 mixture of water-polyethylene glycol (PEG) facilitated the 1,3-dipolar cycloaddition of benzoylnitromethane/ethyl 2-nitroacetate with terminal alkynes or alkenes leading to isoxazoles or isoxazolines under green conditions. The methodology is free from the use of any base, catalyst, dehydrating agent or hazardous solvent.
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