期刊
ADVANCED SYNTHESIS & CATALYSIS
卷 355, 期 16, 页码 3137-3140出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adsc.201300621
关键词
anhydrides; borosilanes; copper; homogeneous catalysis; nucleophilic addition
资金
- Universite catholique de Louvain
The transition metal-catalyzed transfer of silicon nucleophiles onto various electrophiles has recently gained considerable attention, due to the now readily available silicon pro-nucleophiles such as silylboronates. Our interest lies in the addition of such species to acid derivatives for the generation of acylsilanes. We report herein an efficient method to synthesize these compounds, starting from easy-to-form anhydrides, with very good yields.
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