期刊
ADVANCED SYNTHESIS & CATALYSIS
卷 355, 期 2-3, 页码 274-280出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adsc.201200856
关键词
asymmetric catalysis; click chemistry; diastereoselectivity; green chemistry; organocatalysis; recycling organocatalyst
资金
- Department of Science and Technology (DST)
- Department of Biotechnology (DBT)
- Council of Science and Industrial Research (CSIR)
- CSIR India
Click chemistry is combined with organocatalysis to fabricate a multifunctional C3-symmetrical dendritic prolinamide with a hydrophobic aromatic core and hydrophilic triazolinium arms that exhibit high efficiency in catalyzing the asymmetric aldol reaction with cyclic ketones. The catalyst is water-compatible and remains active for five consecutive catalytic runs with a low catalyst loading (2mol%), yielding the aldol products in high yields, diastereo- and enantioselectivities.
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