期刊
ADVANCED SYNTHESIS & CATALYSIS
卷 354, 期 16, 页码 2959-2964出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adsc.201200310
关键词
alkynes; dehydrogenation; Lewis acids; silanes; zinc
资金
- Ministry of Education, Culture, Sports, Science and Technology [24550123]
- Grants-in-Aid for Scientific Research [24550123] Funding Source: KAKEN
A combination of zinc triflate and pyridine in a nitrile medium was found to act as an effective catalytic system for dehydrogenative silylation with flexible pieces of terminal alkynes and hydrosilanes, thereby producing diverse alkynylsilanes in high to excellent yields.
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