期刊
ADVANCED SYNTHESIS & CATALYSIS
卷 355, 期 1, 页码 221-226出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adsc.201200673
关键词
addition and cyclization; iron catalysis; nitroolefins; pyrroles; tandem reaction
资金
- National Natural Science Foundation of China [NSFC 21272183, 21002077]
- Fund of New Scientific Stars of Shanxi Province [2012KJXX-26]
- Fund of Education Department of Shaanxi Provincial Government [12JK0611]
The iron-catalyzed addition and cyclization of the Blaise reaction intermediate and nitroolefins to synthesize highly functionalized NH-pyrroles in a tandem one-pot manner from nitriles has been developed. This reaction shows good functional group tolerance and affords a broad spectrum of substituted NH-pyrroles in good yields.
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