期刊
ADVANCED SYNTHESIS & CATALYSIS
卷 354, 期 14-15, 页码 2727-2733出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adsc.201200170
关键词
asymmetric catalysis; Bronsted acids; hydrogenation; N-hydroxy-a-amino phosphonates; N-hydroxy-a-imino phosphonates; palladium
资金
- Russian Foundation for Basic Researches [N 09-03-01128-a]
The enantioselective synthesis of ring-substituted [N-(hydroxy)amino](phenyl)methylphosphonic esters via asymmetric hydrogenation of the corresponding N-hydroxy-a-imino phosphonates with up to 90% ee was developed using catalytic amounts of palladium(II) acetate and (R)-BINAP in 2,2,2-trifluoroethanol with a Bronsted acid as an activator.
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