期刊
ADVANCED SYNTHESIS & CATALYSIS
卷 354, 期 14-15, 页码 2671-2677出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adsc.201200574
关键词
aerobic oxidative reaction; alcohols; amines; copper catalysis; imine synthesis
资金
- NNSFC [20902070]
- SRF for ROCS of SEM
- NSF [Y4100579]
- QJTP of Zhejiang Province [QJD0902004]
- Post-graduate Innovation Foundation of Wenzhou University [31606036010142]
A general, green, and scalable synthesis of the useful imines and a,beta-unsaturated imines is successfully achieved by a low-loading and powerful, mild and efficient copper-catalyzed aerobic oxidative reaction of alcohols and amines in the open air at room temperature under base- and dehydrating reagent-free conditions. This practical reaction can use air as the economic and green oxidant, tolerates a wide range of substrates, can afford high yields of the target imines on a large scale, and produces water as the only by-product, and thus being the best imination method as yet using alcohols and amines directly.
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