期刊
ADVANCED SYNTHESIS & CATALYSIS
卷 354, 期 8, 页码 1437-1442出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adsc.201200110
关键词
air; aqueous hydrazine; diimide; ferric chloride hexahydrate; olefins; reduction; selectivity
资金
- ARMREB, New-Delhi [ARMREB/EMCB/2009/111]
- Indian Institute of Science
- RL fine Chem
- CSIR, New-Delhi
A chemoselective reduction of olefins and acetylenes is demonstrated by employing catalytic amounts of ferric chloride hexahydrate (FeCl3 center dot 6H(2)O) and aqueous hydrazine (NH2NH2 center dot H2O) as hydrogen source at room temperature. The reduction is chemoselective and tolerates a variety of reducible functional groups. Unlike other metal-catalysed reduction methods, the present method employs a minimum amount of aqueous hydrazine (1.5-2 equiv.). Also, the scope of this method is demonstrated in the synthesis of ibuprofen in aqueous medium.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据