期刊
ADVANCED SYNTHESIS & CATALYSIS
卷 354, 期 5, 页码 818-822出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adsc.201100733
关键词
asymmetric catalysis; iron; ketones; macrocycle ligands; transfer hydrogenation
资金
- National Natural Science Foundation of China [20423002, 20923004, 21173176]
- Program for Changjiang Scholars and Innovative Research Team in University [IRT1036]
- State Key Laboratory of Physical Chemistry of Solid Surfaces
Novel P2N4-donors containing chiral 22-membered macrocyclic ligands have been synthesized and the structures have been determined by an X-ray diffraction study. The catalytic systems in situ generated from triiron dodecarbonyl, Fe3(CO)12, and the chiral macrocyclic ligand exhibited high activity (TOF up to 1940 h-1) and excellent enantioselectivity with up to 99% ee in the asymmetric transfer hydrogenation of various aromatic ketones.
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