4.7 Article

The Role of Metal Hydroxide Complexes in Late Transition Metal-Mediated Transmetalation Reaction: The Case of Gold

期刊

ADVANCED SYNTHESIS & CATALYSIS
卷 354, 期 13, 页码 2380-2386

出版社

WILEY-V C H VERLAG GMBH
DOI: 10.1002/adsc.201200233

关键词

arylboronic acids; gold hydroxide complexes; gold-aryl complexes; N-heterocyclic carbenes; transmetalation

资金

  1. EPSRC
  2. ERC
  3. Royal Society
  4. Engineering and Physical Sciences Research Council [EP/J011053/1] Funding Source: researchfish
  5. EPSRC [EP/J011053/1] Funding Source: UKRI

向作者/读者索取更多资源

In gold chemistry, the hydroxide function on the metal center was observed to act as a potent transmetalation group facilitator when reacted with boronic acids leading to the exceedingly rapid formation of gold-aryl bonds.

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