期刊
ADVANCED SYNTHESIS & CATALYSIS
卷 353, 期 16, 页码 3031-3038出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adsc.201100429
关键词
alcohols; deprotection; 2; 3-dichloro-5; 6-dicyano-1; 4-benzoquinone (DDQ); oxidation; oxygen
资金
- National Natural Science Foundation of China [NSFC 20772111, 20876149, 21146001]
- Zhejiang Provincial Natural Science Foundation of China [Y4090517]
A new catalytic oxidation system using catalytic amounts of 2,3-dichloro-5,6-dicyano-1,4-benzoquinone (DDQ) and tert-butyl nitrite with molecular oxygen serving as the environmentally benign, terminal oxidant has been developed. This aerobic catalytic system was established for the selective oxidation of non-sterically hindered benzylic alcohols and electron-rich benzyl methyl ethers, and successfully extended to an application in the oxidative deprotection of PMB ethers to the alcohols in high selectivity.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据