期刊
ADVANCED SYNTHESIS & CATALYSIS
卷 353, 期 5, 页码 781-787出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adsc.201000807
关键词
aryl halides; C-C coupling; cyanation; formamide; nitriles; palladium
资金
- University Grant Commission, India under Green Technology Centre of Institute of Chemical Technology
A novel method for cyanation of aryl halides using formamide as a non-toxic cyanide source is reported. It is a single-step, solvent-free method wherein formamide itself acts as solvent as well as source of cyanide in the presence of phosphorus oxychloride and palladium acetate/xantphos catalyst. Aryl iodides as well as aryl bromides provided moderate to excellent yields of up to 93%.
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