期刊
ADVANCED SYNTHESIS & CATALYSIS
卷 353, 期 4, 页码 563-568出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adsc.201000952
关键词
BINOL phosphate; enantioselective Friedel-Crafts reaction; organocatalysis; quaternary carbon centers
资金
- Deutsche Forschungsgemeinschaft [1179]
A new enantioselective Bronsted acid-catalyzed Friedel-Crafts reaction of indole with cyclic imines has been develeoped. This organocatalytic reaction provides for the first time optically active indolindolinone derivatives in high yields and with excellent enantioselectivities (up to 91% ee) under mild reaction conditions.
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