期刊
ADVANCED SYNTHESIS & CATALYSIS
卷 353, 期 18, 页码 3295-3300出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adsc.201100591
关键词
green chemistry; photocatalysis; radicals; sulfones; tin-free process
资金
- MIUR
Radical conjugate addition onto vinyl sulfones was achieved by means of a convenient, tin-free procedure. This was based on the photocatalyzed C?H bond activation in aldehydes, amides, ethers and even cycloalkanes by using tetrabutylammonium decatungstate (TBADT). The reaction was likewise effective for the functionalization of beta-substituted vinyl sulfones. The products are useful building blocks and were obtained in satisfactory yields both under artificial UV light and under sunlight, so demonstrating the green potential of the process.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据