期刊
ADVANCED SYNTHESIS & CATALYSIS
卷 353, 期 7, 页码 1161-1168出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adsc.201000962
关键词
alcohols; alkylation; amines; iridium; water-soluble catalyst
资金
- Mitsubishi Chemical Corporation
An efficient and environmentally benign catalytic system for the synthesis of various organic amines catalyzed by the water-soluble and air-stable (pentamethylcyclopentadienyl)-iridium-ammine iodide complex, [Cp*Ir(NH3)(3)][I](2) (Cp* - pentamethylcyclopentadienyl), has been developed. A wide variety of secondary and tertiary amines were synthesized by the N-alkylation reactions of theoretical equivalents of amines with alcohols in water under air without a base. The synthesis of cyclic amines was also achieved by the N-alkylation of benzylamine with diols. Furthermore, the recycle use of the present water-soluble Cp*Ir catalyst was accomplished.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据