期刊
ADVANCED SYNTHESIS & CATALYSIS
卷 353, 期 14-15, 页码 2614-2618出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adsc.201100269
关键词
alkylation; asymmetric synthesis; Michael addition; organocatalysis; phase-transfer catalysis
资金
- JSPS
- MEXT (Japan)
- Grants-in-Aid for Scientific Research [22106519, 22750093] Funding Source: KAKEN
A highly efficient catalytic asymmetric synthesis of 1,1-disubstituted tetrahydroisoquinolines has been achieved via asymmetric alkylation or Michael addition of 1-cyanotetrahydroisoquinolines using binaphthyl-modified N-spiro-type chiral phase-transfer catalysts.
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