期刊
ADVANCED SYNTHESIS & CATALYSIS
卷 352, 期 1, 页码 113-118出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adsc.200900662
关键词
aerobic oxidation; iron chloride; primary alcohols; sodium nitrite; TEMPO
资金
- National High Technology Research and Development Program of China (863 Program) [2008AA06Z306]
- National Natural Science Foundation of China [20572110]
A variety of 4-substituted 2,2,6,6-tetramethylpiperidyl-1-oxy (TEMPO) derivatives has been screened for their ability in the oxidation of primary alcohols to the aldehydes with dioxygen under mild conditions. An evaluation of the efficiency of these 4-substituted TEMPO derivatives in the alcohol oxidation may allow an insight into the effect of the structural variations of TEMPO on the oxidation of alcohols, which should facilitate catalyst design and screening efforts. Based on the screening results of 4-substituted TEMPO derivatives, the catalyst comprised of 4-acetamido-TEMPO, iron chloride and sodium nitrite, has been developed for the highly efficient oxidation of a wide range of primary alcohols including primary aliphatic alcohols to the corresponding aldehydes under mild conditions.
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