期刊
ADVANCED SYNTHESIS & CATALYSIS
卷 352, 期 1, 页码 33-79出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adsc.200900765
关键词
Heck reaction; heterogeneous palladium catalysts; Sonogashira reaction; Suzuki reaction; Tsuji-Trost reaction; water
资金
- Universite de Bordeaux
- Centre National de la Recherche Scientifique (CNRS)
- Association pour la Recherche sur le Cancer (ARC)
- Abou Merhi Charity Institution (AMCI)
This review summarizes the progress made essentially these last ten years on heterogeneous palladium catalysis in pure water. The work covers four important palladium-catalyzed transformations for carbon-carbon bond formation: Suzuki, Heck, Sonogashira and Tsuji-Trost reactions. The discussion focuses on the efficiency and reusability of the heterogeneous catalysts as well as on the experimental conditions from a sustainable chemistry point of view. The review is introduced by a discussion on mechanistic aspects inherent to heterogeneous catalysis.
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