期刊
ADVANCED SYNTHESIS & CATALYSIS
卷 352, 期 2-3, 页码 309-316出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adsc.200900729
关键词
heterocycles; imination; iron catalysis; metal-free conditions; sulfoximines
资金
- Fonds der Chemischen Industrie
- Syngenta
Sulfoximines bearing pyrazolylmethyl and aryl substituents, which are relevant to the crop protection industry, and their corresponding sulfilimine intermediates, have been prepared from sulfide precursors by either iron-catalyzed nitrogen transfer reactions or metal-free imination procedures. Whereas the former approach leads to N-nosyl-substituted products, the latter affords N-cyano derivatives.
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