期刊
ADVANCED SYNTHESIS & CATALYSIS
卷 352, 期 11-12, 页码 1949-1954出版社
WILEY-BLACKWELL
DOI: 10.1002/adsc.201000223
关键词
N-arylamination; C-S cross-coupling; N-heterocyclic carbenes; nickel
资金
- Junta de Andalucia [P07-PQM-02745]
- MEC [CTQ2008-00042BQU]
- Consolider Ingenio 2010 [CSD2006-0003]
The room temperature Buchwald-Hartwig animation of heteroaromatic chlorides has been achieved using the sterically bulky allylnickel chloride/N-heterocyclic carbene [(IPr)Ni(allyl)Cl] complex as a well-defined precatalyst. Arylation of aromatic thiols, affording high yields of products under low catalyst loadings, has also been promoted with the same complex.
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