4.7 Article

Phase-Selective Catalysis in Emulsions Stabilized by Janus Silica-Nanoparticles

期刊

ADVANCED SYNTHESIS & CATALYSIS
卷 352, 期 14-15, 页码 2359-2364

出版社

WILEY-V C H VERLAG GMBH
DOI: 10.1002/adsc.201000479

关键词

emulsion catalysts; heterogeneous catalysis; Janus particles; phase selectivity; Pickering emulsions

资金

  1. NSF [0814361]
  2. DoE [DE-FG36GO88064]
  3. Office Of The Director
  4. EPSCoR [0814361] Funding Source: National Science Foundation

向作者/读者索取更多资源

Metal-containing Janus particles are used as interfacial catalyst/emulsifiers that catalyze reactions in biphasic systems with controlled phase selectivity, that is, conversion of the desired reaction on one side of the emulsion. The reaction may affect the solubility of the molecule in one phase, causing migration to the opposite phase. As a result, combined reaction and separation can be achieved in a single reaction vessel.

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