期刊
ADVANCED SYNTHESIS & CATALYSIS
卷 352, 期 18, 页码 3126-3130出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adsc.201000733
关键词
amido-ligands; asymmetric catalysis; hydrogenation; imines; rhodium
资金
- NANOCAT with Elitenetzwerk Bayern
Novel N,N,P ligand stabilized rhodium complexes exhibiting high activities and enantioselectivities in the asymmetric hydrogenation of N-aryl imines are introduced. The ligands were synthesized from inexpensive starting materials and their modular design allows for the introduction of a broad variety of substitution patterns. Additionally, a rather low catalyst loading could be employed.
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