期刊
ADVANCED SYNTHESIS & CATALYSIS
卷 353, 期 1, 页码 57-63出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adsc.201000429
关键词
aryl alkyl ketones; catalysis; cross-ketonisation; decarboxylation; iron
资金
- NanoKat
- Novartis
- Landesgraduiertenforderung Rheinland-Pfalz
In the presence of catalytic amounts of magnetite nanopowder, mixtures of aromatic and aliphatic carboxylic acids are converted selectively into the corresponding aryl alkyl ketones. As by-products, only carbon dioxide and water are released. This catalytic cross-ketonisation allows the regioselective acylation of aromatic systems and, thus, represents a sustainable alternative to Friedel-Crafts acylations.
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