期刊
ADVANCED SYNTHESIS & CATALYSIS
卷 352, 期 7, 页码 1179-1192出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adsc.200900680
关键词
catalysis; copper; cycloaddition; multicomponent reaction; supported catalysts
资金
- Fond Europe de Desarrollo Social (FEDER)
- Galician Government [PGIDIT06PXIB203299PR]
- Conselleria de Educacion (Xunta de Galicia)
- Xunta de Galicia, Spain
New supported catalysts for the Huisgen's [3 + 2] azide-alkyne cycloaddition have been prepared by immobilization of copper species on commercially available polymeric matrixes incorporating the 1,5,7-triazabicyclo[4.4.0]dec-5-ene (TBD) template. The synergic exploitation of the exceptional copper chelating ability and basicity profile of the TBD framework, in addition to ensuring effective immobilization and stabilization of copper species, allows the implementation of three-component strategies. The new catalytic systems enabled the development of regioselective, efficient, modular, mild and eco-friendly multicomponent syntheses of diversely decorated 1,2,3-triazoles, contributing to expand the scope and versatility of the Cu-catalyzed Huisgen 1,3-dipolar cycloaddition.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据